BOTO3

Boto3 Assume role example: This will work copy paste, just put in your role ARN that you plan to use.

#!/usr/bin/env python3

import boto3

# create an STS client object that represents a live connection to the 
# STS service
sts_client = boto3.client('sts')

# Call the assume_role method of the STSConnection object and pass the role
# ARN and a role session name.
assumed_role_object=sts_client.assume_role(
    RoleArn="arn:aws:iam::account-of-role-to-assume:role/name-of-role",
    RoleSessionName="AssumeRoleSession1"
)

# From the response that contains the assumed role, get the temporary 
# credentials that can be used to make subsequent API calls
credentials=assumed_role_object['Credentials']

# Use the temporary credentials that AssumeRole returns to make a 
# connection to Amazon S3  
s3_resource=boto3.resource(
    's3',
    aws_access_key_id=credentials['AccessKeyId'],
    aws_secret_access_key=credentials['SecretAccessKey'],
    aws_session_token=credentials['SessionToken'],
)

# Use the Amazon S3 resource object that is now configured with the 
# credentials to access your S3 buckets. 
for bucket in s3_resource.buckets.all():
    print(bucket.name)